When the ligand 1,4,5-triazanaphthalene (abbreviated as tan) is reacted with Cu( ii ) BF 4 − and ClO 4 − salts, a variety of mononuclear compounds has been found, all with the (Cu(tan) 4 ) unit and varying amounts of weakly coordinating axial ligands and lattice solvents. Mutikainen, Ilpo Ghazzali, Mohamed Al-Farhan, Khalid Reedijk, Jan Gradual transformation of mononuclear Cu( ii ) compounds via polynuclear mixed-valence Cu( ii )/Cu( i ) species to dinuclear Cu( i ) syntheses, characterizations and X-ray structures Copper perchlorate and tetrafluoridoborate compounds with the ligand 1,4,5-triazanaphthalene.
Copper perchlorate and tetrafluoridoborate compounds with the ligand 1,4,5-triazanaphthalene.
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